Illustrated Glossary of Organic Chemistry - Sigma orbital

Illustrated Glossary of Organic Chemistry

σ orbital (sigma orbital): The bonding molecular orbital component of a σ bond. In this orbital the electron density is located along the bond axis.

A simplified representation of the σ orbital component of the C-F σ bond of methyl fluoride. This is a bonding molecular orbital.

A simplified representation of the σ* orbital component of the C-F σ bond of methyl fluoride. This is an antibonding molecular orbital.

Related terms: Pi orbital, π orbital, pi bond, π bond, atomic orbital, s orbital, p orbital, p_x orbital, p_y orbital, p_z orbital, nonbonding molecular orbital, orbital electronegativity
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