Illustrated Glossary of Organic Chemistry
Pyridinium
chlorochromate (PCC):
A reagent for
chemoselective
alcohol
oxidation
.
Molecular structure
of
pyridinium
chlorochromate. It is a
salt
of the
pyridinium
cation
and chlorochromate
anion
.
Pyridinium
chlorochromate
oxidizes
a
secondary alcohol
(such as
2-propanol
) to a
ketone
(in this case
acetone
).
Pyridinium
chlorochromate
oxidizes
a
primary alcohol
to an
aldehyde
. Unlike
Jones reagent
(which is
aqueous
and strongly
acidic
), PCC (which is
anhydrous
) does not further
oxidize
the
aldehyde
to a
carboxylic acid
.
Related terms:
Pyridine
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