Illustrated Glossary of Organic Chemistry
[4+3]:
A
cycloaddition reaction
in which a four-atom component combines with a three-atom component to form a new seven-membered ring. The reaction may be
intermolecular
or
intramolecular
.
In this
intermolecular
[4+3]
cycloaddition reaction
,
furan
(the four-atom component; shown in red) combines with an
oxy
allyl cation
(the three-atom component; shown in blue) to form a new cyclo
heptane
ring.
Related terms:
Pericyclic reaction
,
sigmatropic reaction
,
[2+2]
,
[3+2]
,
[4+2]
,
Woodward-Hoffmann rules
Wikipedia entry
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