Illustrated Glossary of Organic Chemistry
Exact mass:
In
mass spectrometry
, an
m/z
measured or calculated to several decimal places (usually four).
Nicotine
Molecular formula
: C
10
H
14
N
2
In the
mass spectrum
of
nicotine
the
nominal mass
for
M
= (10 x 12) + (14 x 1) + (2 x 14) = 162
amu
, whereas the exact mass is (10 x 12.0000) + (14 x 1.007825) + (2 x 14.003074) = 162.1157
amu
.
Related terms:
Mass spectrometer
,
molecular ion
,
M+1
,
M+2
,
fragment ion
,
electron impact ionization
,
EI
,
chemical ionization
,
CI
,
MALDI
, g
as chromatography-mass spectrometry
,
GC-MS
Wikipedia entry
Table of exact masses
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