Illustrated Glossary of Organic Chemistry
Equilibrium
constant (
K
eq
):
A ratio that quantifies the position of a chemical
equilibrium
. When the
equilibrium
favors
reactants
Δ
G
> 0 and
K
eq
< 1. When the
equilibrium
favors
products
Δ
G
< 0 and
K
eq
> 1.
A generic
equilibrium
, and
equilibrium
constant expression.
Equilibrium
constant expression for a
mechanism step
involving the
ionization
of
tert
-butyl
bromide
to form
tert
-butyl carbocation
and
bromide ion
.
Related terms:
p
K
a
,
Δ
G
++
,
E
act
,
reaction rate
,
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