Illustrated Glossary of Organic Chemistry
Dieckmann
condensation
:
An
intramolecular
version of the
Claisen condensation reaction
.
In this example of the Dieckmann
condensation reaction
, di
methyl
adipate is reacted with sodium
methoxide
(a strong
base
) in
methanol
(the
solvent
), followed by
aqueous
acid
, to
produce
methyl
2-
oxo
cyclopentane
-1-
carboxylate
, a
cyclic
β-ketoester
.
Related terms:
Ester
,
deprotonation
,
enolate
,
substitution reaction
,
nucleophilic carbonyl substitution
,
nucleophilic acyl substitution
,
condensation reaction
,
β-keto ester
,
beta-keto ester
,
name reaction
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