Illustrated Glossary of Organic Chemistry
ΔE:
An energy difference. In Chem 14C and Chem 14D refers to the energy difference between
quantum mechanical
energy states (rotational, vibrational, electronic,
nuclear spin
, etc.).
The
HOMO
-
LUMO
ΔE (the
HOMO-LUMO gap
) is an important property for
conjugated
molecules
.
In
1
H-NMR spectroscopy
, the
ground state
-
excited state
ΔE controls the energy of radio wave
photon
required for
nuclear spin flip
, and hence the
proton's
chemical shift
.
Related terms:
ΔΕΝ
,
Δ
G
,
Δ
G
++
,
Δ
H
f
o
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