Illustrated Glossary of Organic Chemistry
De
hydration
(desiccation):
A process such as a chemical reaction that removes
water
.
Reaction of 1-
methyl
-1-
cyclohexanol
with
aqueous
sulfuric acid
results in de
hydration
and formation of an
alkene
product
. The atoms which constitute the
molecule
of
water
that is removed are shown in red. The reaction follows the
E1 mechanism
, as shown in this example.
CoCl
2
.
6
H
2
O
Anhydrous
CoCl
2
Gently heating CoCl
2
.
6
H
2
O
(red) causes it to de
hydrate
. The product is
anhydrous
CoCl
2
(blue).
Watch a time lapse video
.
Sucrose
+
H
2
SO
4
Carbon +
water
vapor (steam)
The modern term '
carbohydrate
' is a contraction of 'carbon
hydrate
'.
Carbohydrates
such as
sucrose
(C
12
H
22
O
11
) where once thought of as 'carbon
hydrates
', having one
molecule
of
water
bonded
to each carbon atom, giving a
molecular formula
approximating C
12
(H
2
O)
12
. While this is not an accurate structure for
sucrose
, its reaction with
concentrated H
2
SO
4
(a de
hydrating
agent) does produce carbon and
water
vapor (steam).
Watch a video of this reaction
.
Related terms:
Curved arrow
,
oxonium ion
,
oxonium ion fates
,
carbocation
,
carbocation fates
,
hydration
,
dehydrohalogenation
Wikipedia entry
Return to glossary index