Illustrated Glossary of Organic Chemistry
Deactivator (deactivating
group
):
In
electrophilic aromatic substitution
, an
aromatic
ring
substituent
that decreases
nucleophilicity
and
arenium ion
stability (relative to a hydrogen atom), thereby causing the reaction to be
slower
than the same reaction on
benzene
itself.
When X =
NO
2
the
rate
is less than when X = H, so
NO
2
is an deactivator.
Related terms:
Activator
,
ortho/para director
,
meta director
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