Illustrated Glossary of Organic Chemistry
D:
(1) A
carbohydrate
having the same
stereocenter
absolute configuration
at the second-to-last carbon in its chain (in
acyclic
form) as (
R
)-
glyceraldehyde
(also called
D
-
glyceraldehyde
).
Note that when '
D
' is used to denote
carbohydrate
configuration
, it is of a smaller font than the name of the
carbohydrate
.
When an
acyclic
carbohydrate
structure
is drawn vertically (as shown below), with the
carbonyl group
as close to the top as possible, the
carbohydrate's
configuration
is
D
when the
OH group
of the highest numbered
stereocenter
points to the right.
D
-
glyceraldehyde
D
-
glucose
(2) An
α-amino acid
having the
absolute configuration
shown below. Called
D
because this
amino acid
enantiomer
can (in principle) be
synthesized
from
D
-
glyceraldehyde
.
D
-
serine
D
-
glyceraldehyde
(3) The chemical symbol for
2
H
, the hydrogen
isotope
called
deuterium
. For example,
D
-Cl is
2
H
-Cl.
(4) The
distribution coefficient
.
Related terms:
Stereocenter
,
stereoisomer
,
relative configuration
,
S
,
L
,
d
,
l
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