Illustrated Glossary of Organic Chemistry
Cation
-
pi
interaction (
pi
-
cation
interaction):
A
noncovalent attractive force
between a
cation
and a
pi electron cloud
, usually the
pi electron cloud
of an
aromatic ring
.
Attraction between a potassium
cation
and the
pi electron cloud
of a
benzene ring
.
Related terms:
Van der Waals force
,
anion-cation interaction
,
covalent bond
,
hydrogen bond
,
ion-dipole interaction
,
aromatic-aromatic interaction
,
aromatic stacking
,
pi stacking
,
London force
,
boiling point
,
melting point
,
solubility
,
solvation
,
molecular recognition
Wikipedia entry
Return to glossary index