Solvent |
Formula |
m.p. (oC) |
b.p. (oC) |
Density (g/cm3) |
Dielectric Constant |
tan δ |
Log Kow |
eo(SiO2) |
eo
(Al2O3) |
η(cp) |
P |
UV Cutoff |
Solubility in water |
Health hazards |
Acetic Acid |
CH3COOH |
17 |
118 |
1.049 |
6.2 |
0.174 |
-0.17 |
>0.73 |
large |
1.25 |
6.2 |
260 |
∞ |
Corr. |
Acetone |
CH3(C=O)CH3 |
-95 |
56 |
0.790 |
21.01 |
0.054 |
-0.24 |
0.47 |
0.56 |
0.32 |
5.1 |
330 |
∞ |
|
Acetonitrile |
CH3C≡N |
-48 |
81 |
0.786 |
36.64 |
0.062 |
-0.34 |
0.50 |
0.65 |
0.37 |
5.8 |
190 |
∞ |
|
Benzene |
C6H6 |
5 |
80 |
0.874 |
2.28 |
|
2.13 |
0.25 |
0.32 |
0.65 |
3 |
280 |
0.0720 |
C, M, T |
Carbon
disulfide |
CS2 |
-23 |
77 |
1.263 |
2.64 |
|
1.84 |
0.14 |
0.15 |
0.36 |
|
380 |
0.20 |
C, M, T |
Carbon
tetrachloride |
CCl4 |
-23 |
77 |
1.594 |
2.24 |
|
2.83 |
0.14 |
0.18 |
0.97 |
1.6 |
265 |
0.0820 |
C, M, T |
Chloroform |
CHCl3 |
-64 |
62 |
1.483 |
4.81 |
0.091 |
1.97 |
0.26 |
0.40 |
0.57 |
4.1 |
245 |
0.8220 |
C, M, T |
Cyclohexane |
C6H12 |
7 |
81 |
0.779 |
2.02 |
|
3.44 |
-0.05 |
0.04 |
0.98 |
0.2 |
210 |
|
M, T? |
1,2-Dichloroethane |
C2H4Cl2 |
-35 |
84 |
1.235 |
10.36 |
0.127 |
1.48 |
0.32 |
0.42 |
0.79 |
3.7 |
230 |
0.8720 |
C, M, T |
Dichloromethane |
CH2Cl2 |
-95 |
40 |
1.327 |
8.93 |
0.042 |
1.25 |
0.32 |
0.42 |
0.44 |
3.1 |
235 |
220 |
C, M, T |
Diethyl ether |
CH3CH2OCH2CH3 |
-116 |
36 |
0.714 |
4.27 |
|
0.89 |
0.38 |
0.38 |
0.22 |
2.8 |
218 |
7.520 |
M, T |
1,2-Dimethoxyethane |
CH3OCH2CH2OCH3 |
-58 |
84 |
0.863 |
7.20 |
|
-0.21 |
|
|
0.42 |
|
220 |
∞ |
M, T |
Dimethylsulfoxide |
CH3(S=O)CH3 |
18 |
189 |
1.101 |
47.24 |
0.825 |
-1.35 |
0.41 |
0.62 |
2.24 |
7.2 |
265 |
∞ |
M? |
1,4-Dioxane
|
C4H8O2 |
12 |
101 |
1.034 |
2.22 |
|
-0.27 |
0.49 |
0.56 |
1.54 |
4.8 |
215 |
∞ |
M, T |
Ethanol |
CH3CH2OH |
-114 |
78 |
0.789 |
25.3 |
0.941 |
-0.24 |
0.65 |
0.88 |
1.20 |
5.2 |
210 |
∞ |
M, T |
Ethyl acetate |
CH3COOCH2CH3 |
-84 |
78 |
0.900 |
6.08 |
0.059 |
0.73 |
0.38 |
0.58 |
0.46 |
4.3 |
255 |
8.520 |
M |
Hexane
|
C6H14 |
-95 |
69 |
0.655 |
1.88 |
0.020 |
3.90 |
0 |
0 |
0.31 |
0.01 |
195 |
|
M, T? |
Isopropanol |
(CH3)2CHOH |
-90 |
82 |
0.785 |
20.2 |
0.799 |
0.05 |
0.63 |
0.82 |
2.35 |
4.3 |
210 |
∞ |
T |
Methanol |
CH3OH |
-98 |
65 |
0.791 |
33 |
0.659 |
-0.77 |
0.73 |
0.95 |
0.60 |
5.1 |
210 |
∞ |
T |
Methylethyl
ketone |
C4H8O |
-86 |
80 |
0.805 |
18.51 |
0.079 |
0.29 |
0.39 |
0.51 |
0.43 |
4.5 |
330 |
3510 |
T |
N,N-Dimethylformamide |
C3H7NO |
-61 |
153 |
0.944 |
38.25 |
0.161 |
-1.01 |
0.76 |
0.91 |
0.91 |
6.4 |
270 |
∞ |
|
Nitromethane |
CH3NO2 |
-29 |
101 |
1.382 |
37.27 |
0.064 |
-0.33 |
0.54 |
0.64 |
0.65 |
5.3 |
380 |
1020 |
|
n-Propanol |
CH3CH2CH2OH |
-127 |
97 |
0.804 |
20.8 |
0.757 |
0.25 |
0.60 |
0.82 |
2.30 |
4.3 |
210 |
∞ |
T |
Pentane |
C5H12 |
-130 |
36 |
0.626 |
1.84 |
|
3.39 |
0.00* |
0 |
0.24 |
0 |
195 |
|
M, T? |
Pyridine |
C5H5N |
42 |
116 |
0.982 |
12.4 |
|
0.70 |
|
0.71 |
0.94 |
5.3 |
330 |
∞ |
M, T? |
Tetrahydrofuran |
C4H8O |
-108 |
66 |
0.889 |
7.52 |
0.047 |
0.46 |
0.35 |
0.45 |
0.55 |
4.2 |
220 |
∞ |
T |
Toluene |
C6H5CH3 |
-95 |
111 |
0.867 |
2.38 |
0.040 |
2.73 |
0.23 |
0.29 |
0.59 |
2.4 |
286 |
0.0516 |
T |
Water |
H2O |
0 |
100 |
1.000 |
78.4 |
0.123 |
|
0.82 |
1.29 |
1.00 |
10.2 |
191 |
|
|
Legend:
* = defined values
tan δ=
loss tangent at 2.45 GHz (Microwave)
Log Kow=
partition coefficient of unionized compound between
n-octanol and water
eo
= eluotropic strength
(solvent strength parameter)
P
= polarity index according to Synder
η(cp)
= viscosity of the compound at 20 oC
UV Cutoff = lower limit for the measurement in the UV-Vis spectrum
The solubility is given in g of solute in 100 g water. The
superscript indicates the temperature it was recorded.
Health hazards: Corr=corrosive,
C=carcinogen, M=mutagenic, T=teratogenic
General Rules:
1. Halogenated solvents possess a higher density than non-halogenated solvents.
2. Halogenated solvents are not flammable.
3. Ethers such as tetrahydrofuran and diethyl ether tend to form (explosive) peroxides. Thus, they can only be used for a limited time. Be careful when using them.
4. Low boiling solvents i.e., diethyl ether, dichloromethane, etc. can build up a significant pressure when used in extractions. Make sure that the solutions that you are using are at room temperature or below.