Illustrated Glossary of Organic Chemistry
SOMO:
A
S
ingly
O
ccupied
M
olecular
O
rbital
. A
molecular orbital
occupied by just one electron.
Label
Occupancy
Label
π
3
*
Unoccupied
LUMO
π
2
SOMO and
HOMO
π
1
The
π
molecular orbitals
of the
allyl
radical
.
π
1
is occupied by a pair of electrons, and is a
bonding molecular orbital
.
π
2
is
nonbonding molecular orbital
that is occupied by a single electron; this orbital is the SOMO and
HOMO
.
π
3
*
is an unoccupied
antibonding molecular orbital
; it is the
LUMO
.
Related terms:
HOMO-LUMO gap
,
atomic orbital
,
s
orbital
,
p
orbital
,
p
x
orbital
,
p
y
orbital
,
p
z
orbital
,
hybrid orbital
,
sp
3
orbital
,
sp
2
orbital
,
sp
orbital
,
sigma orbital
,
σ orbital
,
sigma* orbital
,
σ* orbital
,
pi orbital
,
π orbital
,
pi* orbital
,
π* orbital
,
orbital electronegativity
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