Illustrated Glossary of Organic Chemistry
Meta
director
:
In
electrophilic aromatic substitution
, a
substituent
that favors
electrophilic
attack
meta
to the
substituent
. Most
meta
directors are also
deactivators
.
Bromination
of
nitro
benzene
gives
meta
-bromo
nitro
benzene
as the
major product
because the
nitro group
is a
meta
director.
aq.
HONO
2
aq
.
H
2
SO
4
+
Bromobenzene
Ortho
-bromo
nitro
benzene
Para
-bromo
nitro
benzene
Nitration
of bromo
benzene
gives a mixture of
ortho
-bromo
nitro
benzene
and
para
-bromo
nitro
benzene
as the
major products
because the bromine
substituent
is an
ortho/para director
.
Related terms:
Deactivating group
,
activator
,
activating group
,
arenium ion
,
carbocation
,
resonance
,
nitronium cation
,
Lewis acid
,
catalyst
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