Illustrated Glossary of Organic Chemistry
London force (dispersion force; London dispersion force):
A
noncovalent molecular force
caused by attraction of
polarized
electron clouds
. The
electron cloud
polarization
is induced: it is caused when the
electron clouds
repel each another, creating adjacent regions of electron deficiency (
δ
+
) and electron excess (
δ
-
). It has also been suggested the
polarizations
result from random fluctuations in
electron density
.
<---
Far apart
--->
The
electron clouds
of two atoms far apart are not
polarized
.
The
electron clouds
of two atoms in close proximity cause mutual
polarization
, resulting in London forces.
Related terms:
Polarizability
,
hard
,
soft
,
van der Waals force
,
noncovalent molecular force
,
noncovalent molecular interaction
,
anion-cation interaction
,
covalent bond
,
hydrogen bonding
,
ion-dipole interaction
,
cation-pi interaction
,
boiling point
,
melting point
,
solubility
,
solvation
,
molecular recognition
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