Illustrated Glossary of Organic Chemistry
Directing
group
(director):
In
electrophilic aromatic substitution
, a
benzene ring
substituent
that influences
benzene ring
nucleophilicity
and
arenium ion
stability, causing the incoming
electrophile
to favor attack at particular positions on the
benzene ring
.
+
+
Ortho
isomer
Minor product
Meta
isomer
Major product
Para
isomer
Minor product
Bromination
of
nitro
benzene
via
electrophilic aromatic substitution
gives mostly the
meta
product
, so the
NO
2
group
is a
meta director
.
Related terms:
Ortho/para director
,
electron withdrawing group
,
electron donating group
,
resonance
,
inductive effect
,
arenium ion
,
major product
,
minor product
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